Earth Notes: General Bibliography (hart-davis1969reactions)
General public bibliography for EOU and related research. #bibliography #dataset
- [hart-davis1969reactions] Hart-Davis, A. J. and Mawby, R. J. Reactions of π-indenyl complexes of transition metals. Part I. Kinetics and mechanisms of reactions of tricarbonyl-π-indenylmethylmolybdenum with phosphorus(III) ligands (accessed ), The Royal Society of Chemistry, , J. Chem. Soc. A, doi:10.1039/J19690002403, article/pages 2403–2407, language en-gb (article) (BibTeX).
abstract
Reactions of tricarbonyl–indenylmethylmolybdenum with phosphorus ligands yield, in the first instance, products of the same type as those obtained from the analogous -cyclopentadienyl complex. The rates of reaction, both in tetrahydrofuran and in n-hexane, are however appreciably faster than those for the -cyclopentadienyl complex. Possible explanations for this increase in rate are discussed.In all cases, the initial product undergoes a further reaction which is believed to be an isomerization similar to those previously described for complexes of the type (-CH)Mo(CO)(L)I."